- Discussion:
- Characteristics of Metals and Implants:
- has best mechanical properties, as it is strong and has good fatigue resistance;
- it is easily worked and cheap to manufacture;
- serious draw back is the tendency to corrode;
- forged stainless steel has greater yield strength than cast stainless steel, but has lower fatigue strength than other alloys;
- elastic modulus of stainless steel is 12 times EM of cortical (EM of titanium is 6 times of cortical bone)
- w/ THR, because of femoral component fracture with early designs, stainless steel is no longer routinely used;
- from the standpoint of erosion, biocompatibility, and fatigue life, stainless steel is inferior to other superalloys;
- Corrosion Properties:
- corrodes more easily than other materials;
- addition of chromium and molybdenum to stainless steel produces corrosive resistant surface layer;
- chromium creates a protective self regenerating chromium oxide layer that protect against corrosion;
- molybdenum decreases the rate of slow passive dissolution of chromium oxide layer by up to 1000 times
- nickle provides additional corrosion resistance;
- surfaces of all metal implants in the U.S. are covered using nitric acid to form an oxide or hydroxide on their surfaces;
- fretting corrosion:
- a process in which abrasive wear is accompanied by corrosion;
- protective oxide layer on metal is removed by abrasion process;
- because new passivation layer that forms after abrasion is neither as durable nor as chemically inert as original layer, metal is more
susceptible to corrosion;
- this form of corrosion often occurs between screw heads & plates;
- stainless steel & cobalt-chromium alloys are susceptible to fretting corrosion
Original Text by Clifford R. Wheeless, III, MD.
Last updated by Clifford R. Wheeless, III, MD on Sunday, August 4, 2013 9:58 am